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Methyl torsion Raman optical activity in trans-2,3-dimethyloxirane and trans-2,3-dimethylthiirane

โœ Scribed by L.D. Barron; L. Hecht; P.L. Polavarapu


Book ID
108008734
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
151 KB
Volume
48
Category
Article
ISSN
1386-1425

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Under the influence of triethyloxonium tetrafluoroborate in methylene chloride, cis-and trans-2,3-dimethylthiirane are transformed to their corresponding polymers almost instantaneously (at temperatures between 0 and 20 ยฐ) but within a few hours these polymers completely degrade to form a mixture of