Benzene and all mono-, ddi-, tri-, tetra-and pentafluoro substituted defivativos thereof were equilibrated with the corresponding atyl anions in the gas phase. Perfect additivity of the substituent effects on the acidity was observe~ The basicifies were dimini~h~ by 12, 6 and 4 kcal/mol depending on
β¦ LIBER β¦
Methyl substituent effects in the gas-phase acidities of halosubstituted oxygen acids. A realignment with substituent effects in solution
β Scribed by Caldwell, G.; McMahon, T. B.; Kebarle, P.; Bartmess, J. E.; Kiplinger, J. P.
- Book ID
- 126246321
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 421 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0002-7863
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