Methyl N-(4-chlorophenyl)-N′-cyanocarbamimidothioate
✍ Scribed by Lu, Yin-Xiang
- Book ID
- 104491006
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 558 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Short halogen-halogen and sulfur-sulfur interactions have been exploited in the design of supramolecular assemblies. The intermolecular ClÁ Á ÁCl (3.581 A ˚) and SÁ Á ÁS (3.282 A ˚) distances in the crystal structure of the title compound, C 9 H 8 ClN 3 S, are shorter than the sum of the van der Waals radii. Classical N-HÁ Á ÁN and C-HÁ Á ÁN hydrogen bonds also contribute to the stabilization of the crystal structure.
📜 SIMILAR VOLUMES
The title compound, C 14 H 10 ClN 3 O 4 , was obtained by the reaction of N-(4-chlorophenyl)-N 0 -(4-nitrobenzoyl)thiourea with cupric chloride dihydrate. Intermolecular N-HÁ Á ÁO hydrogen bonds link the molecules into centrosymmetric dimers. The crystal packing is further stabilized by weak C-HÁ Á