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Methyl isothiocyanate as a quasi-symmetric top. A reinterpretation of the microwave spectrum

✍ Scribed by Marek Krȩglewski

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 334 KB
Volume: 112
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80549-7

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✦ Synopsis

The skeletal bending-internal rotation potential function for CHBNCS has been determined from the microwave spectrum which sives the heeht of the barrier to linearity at 209 cm-l and the CNC equilibrium angle at 27.5". An accidental near-resonance between the 2' and 33 skeletal bending states is found.

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