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Methyl isocyanide is probably a non-RRKM molecule

โœ Scribed by H.H. Harris; D.L. Bunker


Book ID
103014304
Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
400 KB
Volume
11
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Classical tiajectory calculations strongly indicate that CH3NC isomcrizaticn does not obey the RRKM theory, even under thermal conditions. Recent experimentaf work reinforces this conclusion.


๐Ÿ“œ SIMILAR VOLUMES


Methyl isocyanide is an RRKM molecule af
โœ Delin Shen; Huw O. Pritchard ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 463 KB

Classical trajectory calculations on the methyl isocyanide molecule at energies above 25,000 cm-l confirm that the rate of reaction to methyl cyanide is bimodal, with a very fast rate before 0.1 ps, and a slower rate from then on. We conclude that before 0.1 ps, the reacting molecules are unrandomiz