Methyl isocyanide is an RRKM molecule af
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Delin Shen; Huw O. Pritchard
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Article
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1994
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John Wiley and Sons
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English
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Classical trajectory calculations on the methyl isocyanide molecule at energies above 25,000 cm-l confirm that the rate of reaction to methyl cyanide is bimodal, with a very fast rate before 0.1 ps, and a slower rate from then on. We conclude that before 0.1 ps, the reacting molecules are unrandomiz