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Methyl group migration in the preparation of o-tolyl- and p-xylyldichloroboranes

โœ Scribed by Eggers, C. A.; Kettle, Sidney F. A.

Book ID
126937207
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
406 KB
Volume
6
Category
Article
ISSN
0020-1669

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๐Ÿ“œ SIMILAR VOLUMES

N-(dialkylphosphinoyl)hydroxylamines : P
N-(dialkylphosphinoyl)hydroxylamines : Preparation using N,O-bis(trimethylsilyl)hydroxylamine and migration of simple alkyl groups in the rearrangements of their O-p-nitrobenzenesulphonates
โœ Martin J.P. Harger; P.Andrew Shimmin ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 847 KB

Abstruct : Treatment of &,P(O)Cl with MesSiNI-IOSiM~ gives Pr$P(0)NHOSiMes. which is desilylated by methanol giving P&P(O)NHOH. The 0-p-nitrobenz.enesulphonyI derivative of this rearranges with KOBu' in BuYIH, an isopropyl group migrating from P to N and the phosphonamidate R'P(O)(OBu?NIIpi being fo