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Methyl Ethers of Podophyllotoxin-Related Cyclolignans

✍ Scribed by del Corral, J. M. Miguel; Gordaliza, M.; Castro, M. A.; Morales, L. J.; Lopez, J. L.; Feliciano, A. San

Book ID
126473545
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
493 KB
Volume
58
Category
Article
ISSN
0163-3864

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The configuration of several keto-cyclolignans reiated to podophyllotoxin has been reviewed. Under basic catalysis, the configuration at the C-atom in a -position to the lactone carbonyl group in podophyllotoxone is inverted instead of the C-atom in a-position to the ketone group, as it has been rep