Methyl- and Acetylpalladium(II) Complexes Containing a P,N,O Tridentate Hydrazone Ligand
✍ Scribed by Paolo Pelagatti; Alessia Bacchi; Mauro Carcelli; Mirco Costa; Hans-Werner Frühauf; Kees Goubitz; Corrado Pelizzi; Michele Triclistri; Kees Vrieze
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 346 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-1948
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Optically active titanium complexes Tieta5:eta1-C5R4SiMe2NC6H10 (OCH2Ph)-2Cl2 (R = H, Me), containing a cyclopentadienyl ligand linked to the chiral trans-2-benzyloxycyclohexylamido group, were synthesized and characterized in both enantiomerically pure forms. A single crystal X-ray structure analys
New neutral organometallic palladium(II) complexes, obtained upon treating complexes of the type [PdRX(P ʝ N)] with PPh 3 and AgCF 3 SO 3 and consist predominantly of the [PdPhI(PNMe 2 )] (1), [PdPhI(PC=NMe)] (2), [PdPhI(PC=NEt)] (3), and [PdMeCl(PNMe 2 )] (4), {PNMe 2 means N,N-dimethyl-trans-P,P i