Methyl 6-O-acetyl-β-D-glucopyranoside
✍ Scribed by Lindberg, K. B.
- Book ID
- 114523302
- Publisher
- International Union of Crystallography
- Year
- 1976
- Weight
- 410 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0567-7408
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📜 SIMILAR VOLUMES
In the title compound, C 20 H 23 NO 12 , the pyranoside ring adopts a 4 C 1 chair conformation, with all substituents oriented in equatorial positions. The endocyclic C-O-C angle is in agreement with the geometry of the equatorial glycosidic bond, typical for the -d-4 C 1 pyranoside conformation.
In the crystal structure of the title compound, C 24 H 26 O 9 , molecules are linked by O-HÁ Á ÁO hydrogen bonds, creating a chain of hydrogen-bonded molecules in the c-axis direction.
The molecule of the title compound, C 29 H 35 ClO 15 S, possesses normal geometric parameters. Intermolecular C-HÁ Á ÁO hydrogen-bond interactions are responsible for the supramolecular assembly of the complex molecules into a threedimensional framework.