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Methyl 4-tert-butoxycarbonyl-N-cyanopiperazine-1-carboximidothioate
✍ Scribed by Lan, Bi-Jian ;Guo, Peng ;Zou, Zhen-Guang ;Lu, Yin-Xiang
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 293 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the solid state, the title compound, C 15 H 23 NO 4 , forms centrosymmetric dimers in which individual molecules are linked by intermolecular N-HÁ Á ÁO hydrogen bonds. The pyrrole ring is planar within 0.004 (9) A ˚.
The title compound, C 27 H 39 N 3 O 9 , is a key intermediate in the synthesis of novel -turn mimetics based on electrophilic amination of enantiomerically pure (S)-pyroglutamic acid. The molecule adopts an extended conformation which is not stabilized by either intra-or intermolecular hydrogen bond
The absolute configuration has been determined for the title compound, C 14 H 18 N 2 O 6 S, a fluorescent dipeptide analogue, which can act as a rigid backbone chromophore in peptides. Intermolecular N-HÁ Á ÁO C hydrogen bonds [HÁ Á ÁO = 2.37 (2) A ˚] are observed in the crystal packing.