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Methyl 3-Amino-2,3,6,-trideoxy- l -hexopyranosides in DFT Level Theory Conformational Studies

✍ Scribed by Nowacki, Andrzej; Liberek, Beata


Book ID
126787393
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
564 KB
Volume
112
Category
Article
ISSN
1089-5639

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Conformational difference in the solid s
✍ Masataka Mori; Tatsuji Chuman; Takane Fujimori; Kunio Kato; Akira Ohkubo; Shozo πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 479 KB

The conformational difference of the title compound (1) in the solid state and in solution has been investigated by X-ray crystallography and high-field proton n.m.r. spectrometry. In the solid state, compound 1 adopts the "c,(D) conformation (la), whereas 1 exists preferentially in the 'C4(D) confo