Methyl 2-O-Methyl-α-D-glucopyranoside and its Triacetate
✍ Scribed by Whistler, Roy L.; Kazeniac, Stanley J.
- Book ID
- 127177546
- Publisher
- American Chemical Society
- Year
- 1954
- Tongue
- English
- Weight
- 260 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
As part of a programme involving X-ray crystallographic studies" of cis-and tpuns-fused hexopyranosides, we now report on the crystal structures of methyl 2-~-methyl-~-D-glucop~anoside\* (11, which was obtained by debe~lidenation of methyl 4,~-O-benzyIidene-2-O-methyI-3-O-~-tolylsulfonyl-~-~-glucopy
Methyl derivatives of methyl(methyl-a-D-glucopyranosid)uronate have been separated without derivatization as well as corresponding per-0-trimethylsilyl, trifluoroacetyl and per-0-acetyl derivatives on columns of different polarity. Good separation was obtained with both of the compounds bearing hydr