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Methyl 1,2,4,5,6,10b-hexahydro-8,9-methylenedioxy-2-oxobenzo[d]cyclopenta[b]azepine-4-carboxylate

โœ Scribed by Robinson, P. D. ;Hua, D. H. ;Hong, Y. ;Miao, S. W.


Book ID
114509578
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
313 KB
Volume
48
Category
Article
ISSN
0108-2701

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## Synthesis of 2,4- 6,7,8,9,9methanopyrimido[4,azocine. -Optimization of direct annulation of triaminopyrimidine (I) with cyclohexenone (II) is achieved using acetic acid as solvent in a screw-capped pressure tube that is heated at 120 โ€ข C for 18 hours. Compound (VII) as prototype, its derivative