Methyl 1,2,3-Benzothiadiazole-6-carboxylate
β Scribed by J. H. Carr
- Book ID
- 112122791
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1972
- Tongue
- English
- Weight
- 112 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0022-152X
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π SIMILAR VOLUMES
The title compound, C 12 H 10 O 5 , was prepared as part of our study on obtaining pure regioselective Friedel-Crafts acetylation products. The molecule is planar with no hydrogen bonds found in the crystal structure. The molecules are stacked together throughinteractions (centroid-centroid distance
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.005 A R factor = 0.052 wR factor = 0.148 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 14 H 16 N 2 O 4 S, was synthesized by the reaction of 4-hydroxy-3-methoxybenzaldehyde, thiourea and methyl 3-oxobutanoate in ethanol under reflux. The crystal structure is stabilized mainly through intermolecular N-HΓ Γ ΓS and O-HΓ Γ ΓO hydrogen bonds. The tetrahydropyrimidin-2