Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.005 A Ê R factor = 0.060 wR factor = 0.171 Data-to-parameter ratio = 13.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Methyl 11,2,3,3a-5a-hydroxy-1-methyl-10-oxo-4-phenyl 10H-indeno[1,2-b]furo[3,4-b]pyrrole-3a-carboxylate
✍ Scribed by Selvanayagam, S. ;Joy, Anju ;Velmurugan, D. ;Ravikumar, K. ;Raghunathan, R.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 268 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, C 22 H 21 NO 5 , the pyrrolidine ring and the five-membered ring in the indene group have envelope conformations, while the furan ring adopts a twist conformation. Weak intermolecular C-HÁ Á ÁO interactions link the molecules into centrosymmetric dimers. The crystal packing is further stabilized by van der Waals forces.
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The absolute configuration of the title tetracyclic bis-oxazine, C 14 H 17 N 3 O 5 S, has been determined. It is an unexpected product from the attempt to synthesize a new class of bisoxazolines. The seven-membered lactam ring exhibits four axial (O and N) and one equatorial (S) substituents. The or
Single-crystal X-ray study T = 183 K Mean '(C±C) = 0.003 A Ê R factor = 0.035 wR factor = 0.082 Data-to-parameter ratio = 12.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.