Methods of fractionating polymers by ultrafiltration
β Scribed by R. W. Baker
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 395 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Polyvinylpyrrolidone and dextran polysaccharides have been fractionated by ultrafiltration by using newly developed membranes with sharp molecular weight cutoffs. Three different experimental techniques were employed: (a) batch ultrafiltration by using progressively more retentive membranes; (b) continuous ultrafiltration by using several similar membranes in series; (c) variable pressure ultrafiltration by using a single membrane and varying the applied pressure. Ultrafiltration is shown to be a technique of preparative fraction having the advantages of simplicity, speed, and economy. This resulted in a rapid drop in flu^.^,^
π SIMILAR VOLUMES
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On page 122, Eq. (19) should read:
In this paper we demonstrate that the polydispersity p = M w / g N of narrow polymer fractions can be readily obtained by measuring band broadening and its velocity dependence in a thermal field-flow fractionation (thermal FFF) system. The thermal FFF method is shown to be more accurate than size ex