✦ LIBER ✦
Methodology for translocating the carboxy group in gibberellins: the partial synthesis of 7(6→15βH)abeo-GA4
✍ Scribed by Lewis N. Mander; John V. Turner; Bruce Twitchin
- Book ID
- 104234148
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 218 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The carboxylic acid group has been excised from phytohormone gibberellin A, and relocated on the D-ring, thereb,y generating a new class of gibberellin derivatives related structurally to helminthosporic acid. In a continuation of our investigations into the molecular basis for the phytohormonal activitlt of gibberellins,' we have now developed mild and efficient procedures for excisinq the biologically important R-ring carboxylic acid group and relocating it on the D-ring.