## Abstract Addition and subtraction operators defined on some subspaces of the full CI space are introduced. It is shown that the effect of these operators on Löwdin many‐electron wave functions consists in adding or removing an electron without destroying spin symmetry. Upward and downward recurr
Method of recurrent construction of Löuwdin spin-adapted wave functions. II. Local representation of creation–annihilation operators
✍ Scribed by A. I. Panin
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 513 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0020-7608
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✦ Synopsis
Abstract
Some compositions of the addition and subtraction operators and recurrence relations for the Sanibel‐type coefficients c~u, v~ (n, s, M) generated by these compositions are studied. A local representation of the fermion creation–annihilation operators via the addition and subtraction operators is obtained. Operators of single excitations, coupling, and decoupling operators, in terms of which the unitary group generators can be expressed are defined. The resulting representation of the nonelementary unitary group generators is much more simple than in the Gelfand–Tzetlin basis and in the most general case contains only six logically different terms, each of them possessing quite transparent physical significance.
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