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Method of Establishing the Lewis Acidity of a Metal Fragment Based on the Relative Binding Strengths of Ar-BIAN Ligands (Ar-BIAN = Bis(aryl)acenaphthenequinonediimine)

✍ Scribed by Gasperini, Michela; Ragaini, Fabio

Book ID: 120409581
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 89 KB
Volume: 23
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om034370i

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Synthesis of Ar-BIAN Ligands (Ar-BIAN =

Synthesis of Ar-BIAN Ligands (Ar-BIAN = Bis(aryl)acenaphthenequinonediimine) Having Strong Electron-Withdrawing Substituents on the Aryl Rings and Their Relative Coordination Strength toward Palladium(0) and -(II) Complexes

✍ Gasperini, Michela; Ragaini, Fabio; Cenini, Sergio 📂 Article 📅 2002 🏛 American Chemical Society 🌐 English ⚖ 82 KB

Synthesis of Ar-BIAN Ligands (Ar-BIAN =

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The synthesis of Ar-BIAN ligands (Ar-BIAN ) bis(aryl)acenaphthenequinonediimine) having strong electron-withdrawing substituents on the aryl ring is reported. Most of these derivatives had escaped isolation in a pure form up to now. A quantitative scale of coordination strength of the newly synthesi