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Method for reactivity ratio determination in high-conversion copolymerisations by means of 1H-n.m.r. spectroscopy

✍ Scribed by Natansohn, Almeric

Book ID
104527013
Publisher
Wiley (John Wiley & Sons)
Year
1978
Tongue
English
Weight
245 KB
Volume
10
Category
Article
ISSN
0007-1641

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✦ Synopsis

Abstract

Copolymerisation of methyl methacrylate and styrene is carried out in the n.m.r. spectrometer's sample tube, measuring the comonomer concentration against time evolution. The data are processed according to the integrated Mayo‐Lewis and Fineman‐Ross equations in order to obtain the reactivity ratios values. The applicability, advantages and limits of the method are discussed.

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