Solvent effect on the initial state and
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Olga A.; JΓ‘n Benko; Ol'ga VollΓ‘rovΓ‘; Vladislav Holba
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Article
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1993
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Springer
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English
β 257 KB
Solvent effects on rate constants and activation enthalpies and entropies for the anation of [Cr(NH3)sH20] 2+ by SCN-in aqueous mixtures of MeOH, EtOH, i-PrOH and t-BuOH were analysed into initial and transition state contributions. From kinetic measurements, solubilities of the complex salt and ent