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Methine-selective deuteration of V(acac)3, [Co(acac)2]4, and Al(acac)3

✍ Scribed by Daniel E. Ryan; Koji Nakanishi

Book ID: 102371216
Publisher: John Wiley and Sons
Year: 1995
Tongue: French
Weight: 205 KB
Volume: 36
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2580360611

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✦ Synopsis

Abstract

In solid state NMR studies of transition metal acetylacetonate complexes, peak assignments required complexes deuterated at methine or methyl positions. The preparation of methine‐deuterated complexes—V(acac‐3‐^2^H)~3~, [Co(acac‐3‐^2^H)~2~]~4~, and Al(acac‐3‐^2^H)~3~—is presented. This method is applicable to preparations of methyl‐deuterated complexes as well.

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