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Methanomethenonaphthalenes by base-promoted epoxide isomerization. A convenient synthesis of exo-4-pentacyclo[6.4.0.02,10 .03,7 .05,9]dodecanol

โœ Scribed by Jeffrey R. Neff; J.Eric Nordlander

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
127 KB
Volume
18
Category
Article
ISSN
0040-4039

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Cm irradiation, cyclopentadiene dimer (3 and its enone derivatives (L,s$ are converted easily to the corresponding cage compounds, 5, 16\* 73and84 .." ,' u \_, by intramolecular cycloaddition, whereas the corresponding transformation of a six-membered analog, from cyclohexadiene dimer (9\_) to lO\_,