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Methanolysis of a phosphate triester: a change in mechanism with acidity

✍ Scribed by Gehrke, Stevin H.; Wadsworth, William S.

Book ID
126330145
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
430 KB
Volume
45
Category
Article
ISSN
0022-3263

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Nucleophilic substitution reactions of d
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✍ Enrique A. Castro; Daniela Ugarte; M. Fernanda Rojas; Paulina Pavez; JosΓ© G. San πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 200 KB

## Abstract The reactions of diethyl 4‐nitrophenyl phosphate (**1**) with a series of nucleophiles: phenoxides, secondary alicyclic (SA) amines, and pyridines are subjected to a kinetic study. Under excess of nucleophile, all the reactions obey pseudo‐first‐order kinetics and are first order in the