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Methanol sensor based on the combined electrocatalytic oxidative effect of chitosan-immobilized nickel(II) and the antibiotic cefixime on the oxidation of methanol in alkaline medium

✍ Scribed by Liu, Yong ;Luo, Shenglian ;Wei, Wanzhi ;Liu, Xiaoying ;Zeng, Xiandong


Book ID
106197171
Publisher
Springer-Verlag
Year
2008
Weight
131 KB
Volume
164
Category
Article
ISSN
0344-838X

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## Abstract The kinetics of reversible complexation of oxalatopentaammine cobalt(III) with Ni^2+^ has been investigated in MeOH + water media (0–50 (v/v) % MeOH) at 15.0–35.0Β°C and I = 0.10 mol dm^βˆ’3^. Analysis of rate data indicates that the monobonded complex [(NH~3~)~5~ Β· CoOCOCO~2~Ni]^3+^ in wh