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Methanol: A chemical Trojan horse as the root of the inscrutable U

โœ Scribed by Woodrow C. Monte


Book ID
116745316
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
136 KB
Volume
74
Category
Article
ISSN
0306-9877

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Dimethylsulfoxide as a kinetic booster f
โœ Marion Collinet-Fressancourt; Nathalie Azaroual; Jean-Marie Aubry; Vรฉronique Nar ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 375 KB

The kinetic booster effect of dimethylsulfoxide on the chemical generation of singlet oxygen, 1 O 2 , from the disproportionation of hydrogen peroxide catalyzed by molybdate ions in methanol has been evidenced by detection of the IR luminescence of 1 O 2 at 1270 nm and by 95 Mo NMR spectroscopy. DMS