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Methane dissociative chemisorption on Pt(111) explored by microscopic reversibility

โœ Scribed by V.A. Ukraintsev; I. Harrison


Publisher
Elsevier Science
Year
1993
Weight
433 KB
Volume
286
Category
Article
ISSN
0167-2584

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We have measured the dissociative chemisorption probability of D2 on Pt ( I 1 I ) as a function of molecular oxygen coverage and have found that the dissociation probability decreases linearly with O2 coverage. The results suggest that O2 poisons the chemisorption sterically by blocking approximatel