Methane-based equations of state for a corresponding states reference substance
โ Scribed by Graham Saville; Richard Szczepanski
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 642 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0009-2509
No coin nor oath required. For personal study only.
โฆ Synopsis
Abshw
-Two equations of state have been dcvelopcd, one valid over the reduced temperature range 0.2-26 and the other over 0.35-26. Both are intended for use as reference equations of state in the calculation of thcrmodynamic properties via the principle of corresponding states. The equations arc essentially equations of state for methane in that they reproduce the experimentally measured properties of the fluid phase over the whole region for which they exist (reduced temperatures of 0.47 to 3.3) but the extension to higher temperatures was made by utilizing experimental measurements made on nitrogen and hydrogen. An empirical scheme was used for temperatures below 0.47. lNTRoDtJcTloN
๐ SIMILAR VOLUMES
It is shown that the three sets of reducing constants (the critical constants, the constants of the intermolecular potential, and the unit-compressibility (UC) constants), all of which can be used as reducing factors for the two-constant system of corresponding states and for two-constant equations
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