Methane Activation by Metal-Free Radical Cations: Experimental Insight into the Reaction Intermediate

Mechanistic Insights into the Reversible

Mechanistic Insights into the Reversible Formation of Iodosylarene–Iron Porphyrin Complexes in the Reactions of Oxoiron(IV) Porphyrin π-Cation Radicals and Iodoarenes: Equilibrium, Epoxidizing Intermediate, and Oxygen Exchange

✍ Woon Ju Song; Ying Ji Sun; Sun Kyung Choi; Wonwoo Nam 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 319 KB 👁 1 views

## Abstract We have shown previously that iodosylbenzene–iron(III) porphyrin intermediates (2) are generated in the reactions of oxoiron(IV) porphyrin π‐cation radicals (1) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 afford