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Metathesis of dialkenylsilanes and polymerization of 1,1-dimethyl-1-sila-3-cyclopentene in presence of aluminum-rhenium catalysts

✍ Scribed by E. Sh. Finkel'shtein; E. B. Portnykh; N. V. Ushakov; V. M. Vdovin


Book ID
112442963
Publisher
Springer
Year
1981
Tongue
English
Weight
426 KB
Volume
30
Category
Article
ISSN
1573-9171

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Chemoselectivity in 4-methyl-1,3-pentadi
✍ Pasquale Longo; Fabia Grisi; Antonio Proto; Adolfo Zambelli πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 267 KB

## Abstract The homogeneous catalyst CpTiCl~3~‐MAO is able to produce a random copolymer of 4‐methyl‐1,3‐pentadiene with ethylene. ^13^C NMR analysis of the copolymers shows that after insertion of ethylene units, the next 4‐ymethyl‐1,3‐pentadiene unit can be inserted in either 1,2 or 1,4 arrangeme