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Metathesis of 2-pentene with the W(CO)6/CCl4/hv- system. Role and physical properties of the photogenerated precipitate

โœ Scribed by P.G.M. Schilder; D.J. Stufkens; A. Oskam; J.C. Mol

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
620 KB
Volume
426
Category
Article
ISSN
0022-328X

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Tetrapropylammonium and -phosphonium ions, nPr 4 E ุ‰ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M โ€ซุโ€ฌ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]