Metastability in Supersaturated Solution and Transition towards Chirality in the Crystallization of NaClO3
✍ Scribed by Dr. Zoubir El-Hachemi; Dr. Joaquim Crusats; Prof. Josep M. Ribó; Prof. J. Michael McBride; Dr. Sabino Veintemillas-Verdaguer
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 383 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0044-8249
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Dry carbonic acid has recently been shown to be kinetically stable even at room temperature. Addition of water molecules reduces this stability significantly, and the decomposition (H2CO3 + nH2O --> (n+1)H2O + CO2) is extremely accelerated for n = 1, 2, 3. By including two water molecules, a reactio
The preparation in solution of a number of cyclic triphosphenium ions and their identification by 31 P NMR spectroscopy are described; the crystal and molecular structure of the six-membered cationic ring (as its hexachlorostannate) has been determined.