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Metallosupramolecular Complexes Derived from Bis(benzene-o-dithiol) Ligands

✍ Scribed by Birgit Birkmann; Andreas W. Ehlers; Roland Fröhlich; Koop Lammertsma; F. Ekkehardt Hahn

Book ID
102794215
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
789 KB
Volume
15
Category
Article
ISSN
0947-6539

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Binuclear and polynuclear rhodium comple
Binuclear and polynuclear rhodium complexes containing chiral dithiolate ligands derived from lactic acid
✍ Z. Freixa; E. Martin; S. Gladiali; J. C. Bayón 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB

Two precursors of the chiral dithiolato ligands, di-[(2R)-acetylmercaptopropyl] phthalate and isophthalate, 1 and 2 respectively, were synthesized from (S)-lactic acid. Reactions of 1 and 2 with [Rh 2 (m)-OMe) 2 (cod) 2 ] (cod = 1,5-cyclo-octtadiene) yielded rhodium thiolato complexes of different n