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Metalloradical EPR Signals from the YZ·S-State Intermediates in Photosystem II

✍ Scribed by Kajsa G. V. Havelius; Johannes Sjöholm; Felix M. Ho; Fikret Mamedov; Stenbjörn Styring


Publisher
Springer Vienna
Year
2009
Tongue
English
Weight
602 KB
Volume
37
Category
Article
ISSN
0937-9347

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A new theory of EPR spectra for singlet states of Mn tetramers, allowing spin-hybridizations for component composite spins, is developed to elucidate the origin of the "multiline" EPR signals from the Mn clusters in an S2 state of photosystem II. By computer simulation it is shown that the Mn cluste