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Metalloporphyrin photochemistry

✍ Scribed by K.S. Suslick; R.A. Watson


Book ID
103567940
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
86 KB
Volume
36
Category
Article
ISSN
0162-0134

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The fluorescence spectra of Ga(III), In(N), Ge(IV) and Sn(IV) tetramethyl pyridine porphyrin showed a small stokes shift co 400+ 100 cm-i attributed to the similarity between their ground and excited states. The one and two electron reduction products of the me~lloporphyrins were studied by steady-s

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The phototoxicities of six metalloporphyrin dimethylesters (i.e. cobalt (Co), copper (Cu), manganese (Mn), nickel (Ni), tin (Sn) and zinc (Zn) were investigated. Hemolysis of human erythrocytes and inactivation of two enzymes (acetylcholinesterase and beta-galactosidase) were used to assess the phot