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Metallocenes of the alkaline earth metals and their carbene complexes

✍ Scribed by Herbert Schumann; Jochen Gottfriedsen; Mario Glanz; Sebastian Dechert; Jörg Demtschuk

Book ID
108346776
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
316 KB
Volume
617-618
Category
Article
ISSN
0022-328X

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The reaction of lithium[bis(dimethylphosphanyl)(trimethyl-(SiMe 3 )] 3 } -(8) was obtained. This compound is not only the first reported hexacoordinated magnesate, but also the first silyl)methanide] Li[(PMe 2 ) 2 C(SiMe 3 )] with BeCl 2 gave the homoleptic compound Be[(PMe 2 ) 2 C(SiMe 3 )] 2 (5) w