Metallocene/methylaluminoxane-catalyzed copolymerizations of oxygen-functionalized long-chain olefins with ethylene
✍ Scribed by Kimmo Hakala; Tuulamari Helaja; Barbro Löfgren
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 130 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-624X
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✦ Synopsis
Copolymerizations of ethylene with 10-undecen-1-ol, 10-undecenyl methyl ether, 10-undecenyl trimethyl silyl ether, and 1-undecene were performed with racethylene-bis(1-indenyl)zirconium dichloride as a catalyst and methylaluminoxane as a cocatalyst. All three oxygen-functional comonomers copolymerized with ethylene, although the activity of the catalyst decreased considerably compared with the homopolymerization of ethylene. The conversions of the comonomers varied from 17 to 40%, depending on the amount of comonomer in the feed. Under the same conditions, the conversion of 1-undecene was 50 -75%. The incorporation (0.7-3.6 mol %, depending on the feed) and the effect on the activity of the catalyst were on the same level for all the functional comonomers, which indicates that trimethylsilyl or methyl groups do not act as effective protecting groups for oxygen atoms. According to NMR and Fourier transform infrared analyses, the final functional group in the copolymers of the trimethylsilyl ether comonomer was hydroxyl. In contrast, the methyl ether group remained untouched in the copolymer, which suggests that the formation of aluminum alkoxides via a reaction with a cocatalyst is not a prerequisite for comonomer incorporation.
📜 SIMILAR VOLUMES
## Abstract Poly(ethylene‐__co__‐propylene) macromonomer (EPM) was synthesized in a high‐temperature continuous stirred tank reactor (CSTR) with [C~5~Me~4~(SiMe~2~N^t^Bu)]TiMe~2~ (CGC‐Ti) as the catalyst system. PE samples with EPM long chain branching (LCB) were produced by semi‐batch copolymeriza