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Metallo-Supramolecular Initiators for the Preparation of Novel Functional Architectures

✍ Scribed by Ulrich S. Schubert; Marcel Heller


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
265 KB
Volume
7
Category
Article
ISSN
0947-6539

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✦ Synopsis


Polymeric materials containing coordinative units have become a field of increasing interest. The combination of inorganic metal-containing units and macromolecules leads to supramolecular structures with new properties. One promising approach to such systems is the application of metallo-supramolecular initiators for living and controlled polymerization methods. The utilization of bi- and terpyridine units and complexes for this purpose will be discussed in this article.


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Synthesis of Functionalized NMP Initiato
✍ Sven Fleischmann; Hartmut Komber; Dietmar Appelhans; Brigitte I. Voit πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 224 KB

## Abstract A novel NMP initiator functionalized with an alkyne group was synthesized and its polymerization behavior investigated. It was shown that the synthesized alkyne end‐functionalized polymers exhibit a linear relationship between calculated number‐averaged molecular weight and the experime