Metallo-Supramolecular Initiators for the Preparation of Novel Functional Architectures
β Scribed by Ulrich S. Schubert; Marcel Heller
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 265 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0947-6539
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β¦ Synopsis
Polymeric materials containing coordinative units have become a field of increasing interest. The combination of inorganic metal-containing units and macromolecules leads to supramolecular structures with new properties. One promising approach to such systems is the application of metallo-supramolecular initiators for living and controlled polymerization methods. The utilization of bi- and terpyridine units and complexes for this purpose will be discussed in this article.
π SIMILAR VOLUMES
## Abstract A novel NMP initiator functionalized with an alkyne group was synthesized and its polymerization behavior investigated. It was shown that the synthesized alkyne endβfunctionalized polymers exhibit a linear relationship between calculated numberβaveraged molecular weight and the experime