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Metallinduzierte und basenkatalysierte 2-Propinyl-Allenyl-Umlagerung in [(HCCCH2)(2,4,6-tBu3C6H2O)]PMoCP(CO)2

✍ Scribed by Leise, Michael ;Lang, Heinrich ;Imhof, Wolfgang ;Zsolnai, Laszlo


Publisher
Wiley (John Wiley & Sons)
Year
1993
Tongue
English
Weight
415 KB
Volume
126
Category
Article
ISSN
0009-2940

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Addition des O'Donnell Reagenzes [Ph2C=N
✍ Theodor Ederer; Karlheinz Sünkel; Wolfgang Beck 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 126 KB 👁 1 views

The addition of [Ph 2 C=NCHCO 2 Me] ± to [(C 6 H 7 )Fe(CO) 3 ] + , [(C 7 H 9 )Fe(CO) 3 ] + , [(C 7 H 7 )M(CO) 3 ] + (M = Cr, Mo) and [(C 2 H 4 )Re(CO) 5 ] + gives derivatives of aamino acids with organometallic side chains. The structure of [(g 4 -C 6 H 7 )CH(N=CPh 2 )CO 2 Me]Fe(CO) 3 was determined