✦ LIBER ✦

Metallic Thin Films of TTF[Ni(dmit)2]2 by Electrodeposition on (001)-Oriented Silicon Substrates

✍ Scribed by D. de Caro; J. Fraxedas; C. Faulmann; I. Malfant; J. Milon; J.-F. Lamère; V. Collière; L. Valade

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 221 KB
Volume: 16
Category: Article
ISSN: 0935-9648
DOI: 10.1002/adma.200306427

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✦ Synopsis

Thin films of organic metals generally exhibit activated conductivity caused by intergrain conduction barriers. One of the few examples of thin films showing truly metallic character is TTF[Ni(dmit)~2~]~2~. Films electrodeposited on silicon substrates remain metallic down to 12 K in spite of their polycrystalline morphology (see Figure).