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Metallation of Pyridines and Quinolines in the Presence of a Remote Carboxylate Group. New Syntheses of Heterocyclic Quinones.

✍ Scribed by Anne-Sophie Rebstock; Florence Mongin; Francois Trecourt; Guy Queguiner


Book ID
111699563
Publisher
John Wiley and Sons
Year
2004
Weight
118 KB
Volume
35
Category
Article
ISSN
0931-7597

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Pyridine hydrochloride: a new reagent fo
✍ Florence Mongin; Olivier Mongin; FranΓ§ois TrΓ©court; Alain Godard; Guy QuΓ©guiner πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 French βš– 214 KB

Pyridine hydroehloride has been widely used in the cleavage of ethers. It is shown herein that this reagent is also efficient for the synthesis of chloro compounds starting from the corresponding bromo derivatives in n-deficient series such as pyridine and quinoline. Thus, for example, 7-bromo-8-hyd