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Metallamacrocyclic complexes of Ni(ii) with 3,3,3?,3?-tetraalkyl-1,1?-aroylbis(thioureas): crystal and molecular structures of a 2 : 2 metallamacrocycle and a pyridine adduct of the analogous 3 : 3 complex

✍ Scribed by Hallale, Oren; Bourne, Susan A.; Koch, Klaus R.


Book ID
121405253
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
518 KB
Volume
7
Category
Article
ISSN
1466-8033

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The dimesitylplatinum(II) complex PtMes 2 (dppz) (Mes = mesityl = 2,4,6-trimethylphenyl) crystallizes with one equivalent of toluene (C 43 H 40 N 4 Pt, monoclinic, P2 1 /c, Z = 4, a = 14.3551(14) A Ê , b = 15.8319(14) A Ê , c = 15.369(2) A Ê , b = 96.784( 6)°). The (dppz)Pt(C1 Mes ) 2 part of the mo