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Metalation of Tris(trimethylsilyl)- and Tris(dimethylphenylsilyl)methane with Methylsodium: The First Dialkylsodate

✍ Scribed by Dr. Salih S. Al-Juaid; Prof. Colin Eaborn; Dr. Peter B. Hitchcock; Dr. Keith Izod; Dr. Michael Mallien; Dr. J. David Smith

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
393 KB
Volume
33
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

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trimethylsilyl)silanes / (Chloromethylene)ammonium chlorides Tris(trimethylsilyl)silyllithium (1) reacts with dialkyl-5c: 1.99 and 1.97 A ˚) and an extreme widening of the SiΟͺCΟͺSi angles at the central sp 3 -carbon atoms (5a: 132.6Β°; (chloromethylene)ammonium chlorides (molar ratio 2:1) to give the

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Treatment of dichloromethyl-tris(trimethylsilyl)silane (Me 3 Si) 3 SiΒ±CHCl 2 (1), prepared by the reaction of tris(trimethylsilyl)silane with chloroform in presence of potassium tertbutoxide, with organolithium reagents (molar ratio 1 : 3) affords the bis(trimethylsilyl)methyl-disilanes Me 3 SiSiR 2