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Metalated carboxylic acids v. thermal condensation of silylated ketene acetals with aromatic aldehydes

✍ Scribed by P.L. Creger

Book ID: 104236347
Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 99 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)84244-1

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✦ Synopsis

Metalated carboxylic acids react with carbonyl compounds with varying success depending upon steric effects in each of the reaction partners.l Given a delocalized structure for the metalated intermediate,2 addition to a carbonyl group is the result of a reorganization of the double bonds in the reactants.

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