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Metal Triflate Catalyzed Regio- and Stereoselective Friedel—Crafts Alkenylation of Arenes with Alkynes in an Ionic Liquid: Scope and Mechanism.

✍ Scribed by Mi Young Yoon; Jin Hong Kim; Doo Seoung Choi; Ueon Sang Shin; Jin Yong Lee; Choong Eui Song

Publisher
John Wiley and Sons
Year
2007
Weight
57 KB
Volume
38
Category
Article
ISSN
0931-7597

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Metal Triflate-Catalyzed Regio- and Ster
Metal Triflate-Catalyzed Regio- and Stereoselective Friedel–Crafts Alkenylation of Arenes with Alkynes in an Ionic Liquid: Scope and Mechanism
✍ Mi Young Yoon; Jin Hong Kim; Doo Seoung Choi; Ueon Sang Shin; Jin Yong Lee; Choo 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 2 views

## Abstract In the metal triflate‐catalyzed hydroarylation of alkynes, employing an ionic liquid dramatically enhanced the catalytic activities, resulting in broadening the scope of substrates (arenes and alkynes). In some cases, even reactions that were not possible in conventional organic solvent