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Metal Tetrahydroborates and Tetrahydroborato Metalates. 20. Reactions of Cadmium Tetrahydroborate with Alcoholates and Phenolates - X-ray Structure of [MeCd(OCMe3)]4

✍ Scribed by Nöth, Heinrich ;Thomann, Martina


Book ID
102787772
Publisher
Wiley (John Wiley & Sons)
Year
1995
Tongue
English
Weight
557 KB
Volume
128
Category
Article
ISSN
0009-2940

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The reactions of titanium(III) and (IV) chlorides with the crown thioether [93aneS3 were investigated. [TiCt 3-(MeCN)3 ] gives a purple 1:1 adduet with a proposed octahedral structure involving tridentate foe-attachment of the ligand. With [TiClg(MeCN)2] the identity of the yellow 1:1 adduct obtaine