Metal Pyrazolato Complexes. Synthesis, Characterization, and X-ray Powder Diffraction Studies of Group 12 Coordination Polymers
β Scribed by Masciocchi, Norberto; Ardizzoia, G. Attilio; Maspero, Angelo; LaMonica, Girolamo; Sironi, Angelo
- Book ID
- 127193928
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 122 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The mononuclear complexes [Re(CO) 3 (Hpz) 2 Br] (1) and [Re(CO) 3 (py)(Hpz)(pz)] species (6). The analogues of 4 and 6 with Hdmpz, i.e. [Re(CO) 3 (Hdmpz) 2 (dmpz)] ( ) and [Re(CO) 3 (Hdmpz) 2 Br] (2) were obtained by treating [Re(CO) 5 Br] with pyrazole (Hpz) or 3,5-dimethylpyrazole [Re(CO) 3 (py)(H
By reacting [Re(CO) 3 (Hpz) 2 (pz)] (Hpz = pyrazole) with characterized in the solid state by single crystal X-ray diffraction analysis and were showed to contain Reβ’β’β’Mn [Mn(CO) 5 Br] in toluene in the presence of Et 3 N, the dinuclear complex [(CO) 3 Re(pz) 3 Mn(CO) 3 ](Et 3 NH) (1) was interactio
By treating [(CO) 3 Re(Hpz) 2 (pz)] (Hpz = pyrazole) with complexes 1a-c with cyclohexyl isocyanide (c-C 6 H 11 NC) afforded the derivatives {(CO) 3 Re(pz) 3 [M(c-C 6 H 11 NC)] 2 } (2a-[Cu(CH 3 CN) 4 ]BF 4 , AgNO 3 , or [Au(tht)Cl] (tht = tetrahydrothiophene) in acetonitrile in the presence of Et 3