The reaction of InCl 3 with LiAs t Bu 2 in THF at ±78 °C gives the indium arsenide Cl 2 InAs t Bu 2 (1), which is dimer in solution and solid state. The corresponding reaction of InCl 3 with Li 2 As t Bu leads to the metalate [Li(THF) 4 ] 2 [(InCl) 4 (InCl 2 ) 2 (As t Bu) 6 ] (2). The arsanido metal
✦ LIBER ✦
Metal phosphanido and metal arsanido cage compounds of aluminium, gallium and indium
✍ Scribed by Bernhard Neumüller; Effat Iravani
- Book ID
- 104010684
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 657 KB
- Volume
- 248
- Category
- Article
- ISSN
- 0010-8545
No coin nor oath required. For personal study only.
✦ Synopsis
This article presents a comparison of phosphanido and arsanido complexes of the metals aluminium, gallium and indium with cage structure. The synthesis and the structures have been discussed especially with respect to the structures of ME (M = Al, Ga, In; E = P, As).
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