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Metal oxo complexes as catalysts for the isomerisation of allylic alcohols

✍ Scribed by Stéphane Bellemin-Laponnaz; Jean-Pierre Le Ny

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
147 KB
Volume
5
Category
Article
ISSN
1631-0748

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✦ Synopsis

The 1,3-allylic rearrangement of allylic alcohols is an important transformation in organic synthesis and various methods for effecting such a transposition have been reported. This short review will focus on the development of transition metal oxo complexes as catalysts for the isomerisation of allylic alcohols. Mechanistic investigations are also discussed.

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Silica immobilised palladium phosphine complexes as recyclable, regioselective catalysts for the allylic alkylation
✍ Albertus J Sandee; Dragana Dimitrijevic; Richard J van Haaren; Joost N.H Reek; P 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 128 KB

The covalent immobilisation of palladium phosphine complexes on silica is demonstrated to be a viable method for the recovery of allylic alkylation catalysts. Both bidentate and monodentate phosphine ligands form stable palladium catalysts that could be recycled without catalyst deterioration and me