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Metal-metal bonded complexes of the early transition metals. 10. Tertiary alkylphosphine adducts of tetrakis(trifluoroacetato)dimolybdenum (Mo2(O2CCF3)4)

โœ Scribed by Santure, D. J.; Sattelberger, A. P.


Book ID
126117676
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
761 KB
Volume
24
Category
Article
ISSN
0020-1669

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Transition metal catalyzed oxidations, 3
โœ Krohn, Karsten ;Rieger, Hagen ;Hopf, Henning ;Barrett, David ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 440 KB

Treatment of I-hydroxy[2.2]paracyclophane (1) with the Mim-(4). This dienone dimerizes at room temperature to afford the oun molybdenum oxodiperoxo complex [Mo(O&O] . Py . Diels-Alder adduct 5, whose structure was confirmed by X-ray HMPT gives 3,4-dihydro-3-hydroxy-4-oxo[2.2]paracyclophane analysis.